(1)預處理
反滲透系統的效率和壽命與原水的預處理效果密切相關。通過預處理可以有效地減少進水對膜的污染、結垢、損傷風險,使膜的使用壽命延長,降低運行費用。
(2)進水的pH值
pH值的高低對膜系統的性能也有很大的影響,垃圾滲濾液在進入DTRO之前需將pH值調為酸性,一方面可以防止難溶無機鹽結垢,另一方面可以使滲濾液中游離氨與加入的酸形成二價氨鹽,而DTRO對類似多價離子的截留率很高,這就能提高最難去除的氨氮的去除率。
改變進水pH值會對反滲透膜的透過性產生影響,隨著pH值的逐漸升高,透過液的流量與pH值成反比,pH值越高,透過液流量越小,但在pH值大于7后出現了拐點,之后pH值繼續升高,透過液流量反而增大。因此,進水pH值偏酸性或偏堿性均有利于提高產水通量。
垃圾滲濾液水質本身極為復雜性且含鹽量高,隨著系統的運行,難溶鹽易在系統末端積聚最終使膜片結垢影響透水量。所以,反滲透處理進水的pH值需控制為酸性,同時考慮后續減少加堿量,可將進水pH值范圍控制在6左右。
(3)系統的運行壓力
反滲透系統的運行壓力是影響反滲透技術運行成本的最重要因素,對反滲透膜的正常使用也有極其重要的影響。由于滲濾液水質的特點,較高的壓力有利于對污染物的截留。但是較高的壓力也更容易造成膜組件的堵塞和污染。 膜系統的產水通量與運行壓力近似呈現出線性關系。同時,膜系統的脫鹽率也隨進水壓力的增大而升高。
(4)系統的回收率
回收率是反滲透的重要指標, 定義為透過液的體積除以原液體積。將電導率20000μs/cm 的滲濾液作為研究對象,控制進水壓力在4.0MPa左右。調節回流泵同時調節控制閥,使進水流量與透過液產水量同步提升,從而改變膜組件的回收率,系統回收率與透過液通量成反比。這是因為反滲透過程是一個在進水端施加壓力逆轉稀溶液向濃溶液自然滲透的過程。
膜組件的脫鹽率與透過液通量成正比, 這是因為低透過液通量時,進水側的鹽濃度相對較高,較大的鹽通量和較低的透過液通量自然會出現脫鹽率較低的結果。
(5)進水溫度的影響
溫度對膜片本身性能的影響十分嚴重, 隨著溫度的升高,水粘度逐漸下降,產水通量會逐漸升高。在對膜系統設計時應充分考慮溫度對膜截留率的影響因素, 通過膜片廠商提供的修正系統以及其他方式, 將運行參數標準化有利于準確掌握系統的運行狀況。
隨著溫度的升高,膜片的脫鹽率逐漸降低,透過液的色度升高且水質變差。這是因為隨著溫度的升高,鹽分透過膜片的擴散速率將逐漸加快,最終大于水透過膜片的速率,表現為膜片脫鹽效率的降低。


(1) preprocessing
The efficiency and life of reverse osmosis system are closely related to the pretreatment effect of raw water. Pretreatment can effectively reduce the fouling, scaling and damage risk of the influent, prolong the service life of the membrane and reduce the operation cost.
(2) the pH value of the influent
The pH value also has a great influence on the performance of the membrane system. The landfill leachate needs to turn the pH value into acidity before entering the DTRO. On the one hand, it can prevent the insoluble inorganic salts from scaling. On the other hand, the free ammonia in the leachate and the added acid can form the two valence ammonia salt, and the retention of the DTRO like polyvalent ions is very high. It can improve the removal rate of ammonia nitrogen which is the most difficult to remove.
The change of the pH value of the influent will affect the permeability of the reverse osmosis membrane. With the increasing of the pH value, the flow flow is inversely proportional to the pH value. The higher the pH value, the smaller the flow flow, but the inflection point after the pH value is greater than 7, and then the pH value continues to rise and the flow flow increases. Therefore, the pH value of the influent is acidic or alkaline, which is conducive to increasing the water production flux.
The water quality of landfill leachate itself is very complex and has high salt content. With the operation of the system, the insoluble salts are easily accumulated at the end of the system and eventually make the scale of the diaphragm affect the permeability. Therefore, the pH value of the reverse osmosis water treatment should be controlled to be acidic. At the same time, the pH value range of the influent can be controlled to about 6 when considering the reduction of alkali addition.
(3) the operating pressure of the system
Reverse osmosis system operation pressure is the most important factor affecting the operation cost of reverse osmosis technology, and has a very important impact on the normal use of reverse osmosis membrane. Because of the characteristics of leachate, higher pressure is favorable for the interception of pollutants. But higher pressure is also more likely to cause blockage and pollution of membrane modules. There is a linear relationship between the flux and the operating pressure of the membrane system. At the same time, the desalination rate of membrane system increases with the increase of influent pressure.
(4) the recovery rate of the system
The recovery rate is an important index of reverse osmosis, which is defined as the volume of liquid through the volume divided by the volume of the original solution. The leachate with conductivity of 20000 s/cm was used as the research object to control the influent pressure of 4.0MPa. The reflux pump regulates the control valve at the same time, so as to synchronize the flow of water with the water output of the liquid, so that the recovery rate of the membrane module is changed, and the recovery rate of the system is inversely proportional to the flux through the liquid. This is because the reverse osmosis process is a process of applying pressure at the inlet end to reverse the natural infiltration of dilute solution into concentrated solution.
The desalination rate of the membrane component is proportional to the permeation flux, which is due to the relatively high salt concentration in the inlet side, and the relatively low desalination rate of the larger flux and the lower permeation flux.
(5) influence of water inlet temperature
The effect of temperature on the performance of the membrane is very serious. With the increase of temperature, the viscosity of water gradually decreases and the water production flux gradually increases. In the design of the membrane system, the influence factors of the temperature on the film interception should be fully considered. Through the correction system provided by the diaphragm manufacturers and other ways, the standardization of the operating parameters is beneficial to the accurate control of the operating condition of the system.
With the increase of temperature, the desalination rate of membrane decreases, the color of permeation liquid increases and the water quality becomes worse. This is because with the increase of temperature, the diffusion rate of the salt through the diaphragm will increase gradually, which is greater than the rate of water passing through the diaphragm, which shows the decrease of the desalination efficiency of the diaphragm.